Stereoselective Nitroolefination of Active Methine of Various Carbonyl Compounds with β-Nitroenamines

DOI: 10.1055/s-1987-28065

Source and publish data:

Synthesis p. 729 - 732 (1987)

Update date:2022-08-05

Topics: Catalyst Solvent Temperature Additives

Authors:

Node, Manabu

Nagasawa, Hideko

Naniwa, Yoshimitsu

Fuji, Kaoru

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Article abstract of DOI:10.1055/s-1987-28065

Enolates of carbonyl compounds having a methine α-carbonyl undergo 2-nitro-1-alkenylation (nitroolefination) to form quarternary C-atom next to the carbonyl group on reaction with β-nitroenamines via an addition elimination process.The geometry of the res

Full text of DOI:10.1055/s-1987-28065

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