Reductive Cleavage of the O-C(8) Bond in 5'-O,8-Cycloadenosines. Intramolecular Protection of the 8-Position and the 5'-Hydroxy Group in Adenosines

DOI: 10.1039/c39870001298

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1298 - 1299 (1987)

Update date:2022-08-04

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Authors:

Sako, Magoichi

Saito, Takao

Kameyama, Keiji

Hirota, Kosaku

Maki, Yoshifumi

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Article abstract of DOI:10.1039/c39870001298

Upon treatment with NaBH3CN in acetic acid at ambient temperature, N⁶-acyl-5'-O,8-cycloadenosines (1) with or without carbon functional groups on the 2-position undergo exclusively a reductive O-C(8) bond cleavage to give the corresponding N View More

Full text of DOI:10.1039/c39870001298

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