Regio- and stereoselectivity of captodative olefins in 1,3-dipolar cycloadditions. A DFT/HSAB theory rationale for the observed regiochemistry of nitrones

DOI: 10.1021/jo001393n

Source and publish data:

Journal of Organic Chemistry p. 1252 - 1263 (2001)

Update date:2022-07-31

Topics:

Authors:

Herrera Herrera

Nagarajan

Morales Morales

Mendez Mendez

Jimenez-Vazquez

Zepeda Zepeda

Tamariz Tamariz

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Article abstract of DOI:10.1021/jo001393n

Captodative olefins 1-acetylvinyl carboxylates proved to be highly regioselective dipolarophiles in 1,3-dipolar cycloadditon to propionitrile oxide, arylphenylnitrile imines, diazoalkanes, and nitrones to yield the corresponding 5-substituted heterocycles

Full text of DOI:10.1021/jo001393n

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