Tetrahedron Letters p. 1435 - 1436 (1988)
Update date:2022-08-05
Topics:
Ranganathan, S.
Singh, W. P.
The crystalline 2-thionaphthylmethyl isocyanide (1), prepared from the novel N-(formamidomethyl)-N-benzyl morpholinium iodide (2), via transfer of elements of CH2NHCHO, is totally devoid of pervasive odour.The cyclo-addition of the conjugate base of (1) to nitriles followed by desulfurization, under very mild conditions, provides an attractive route to imidazoles.
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(2009)Doi:10.1080/15421400802305780
(2008)Doi:10.1021/om900038u
(2009)Doi:10.1055/s-0028-1087913
(2009)Doi:10.1016/S0040-4039(00)96760-1
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