Tetrahedron Letters p. 5883 - 5886 (1987)
Update date:2022-08-04
Topics:
Hori, Kimihiko
Ando, Masatomo
Takaishi, Naotake
Inamoto, Yoshiaki
Bridgehead acid chlorides 1a and 1b react with activated alkenes 2 in the presence of a catalytic amount of palladium and 1 equiv of a tertiary amine.The reaction proceeds regio- and stereoselectively at the terminal carbon atoms to yield acylated alkenes 3 with E-configuration.
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