CATALYTIC OSMYLATION OF ELECTRON POOR ALLYLIC ALCOHOLS AND ETHERS. A SYNTHETIC APPROACH TO BRANCHED CHAIN SUGARS

DOI: 10.1016/S0040-4020(01)85840-3

Source and publish data:

Tetrahedron p. 491 - 502 (1988)

Update date:2022-08-04

Topics:

Authors:

Bernardi, Anna

Cardani, Silvia

Scolastico, Carlo

Villa, Roberto

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Article abstract of DOI:10.1016/S0040-4020(01)85840-3

The catalytic osmylation of electron-poor allylic ethers and alcohols was studied.In the case of γ-alkoxy E-enoates reaction selectivity was found to range from 2:1 to 8:1 in favor of the arabino (2,3-syn - 3,4-anti) product, regardless of the double bond

Full text of DOI:10.1016/S0040-4020(01)85840-3

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