A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: Resolution of racemic allylic carbonates

DOI: 10.1021/ol901031b

Source and publish data:

Organic Letters p. 3140 - 3142 (2009)

Update date:2022-08-02

Topics:

Authors:

Vrieze, Derek C.

Hoge, Garrett S.

Hoerter, Perrine Z.

Van Haitsma, Jared T.

Samas, Brian M.

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Article abstract of DOI:10.1021/ol901031b

A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.

Full text of DOI:10.1021/ol901031b

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