Journal of Organic Chemistry p. 140 - 145 (1989)
Update date:2022-08-04
Topics:
Cantrell, Thomas S.
Allen, Andrew C.
Ziffer, Herman
Methyl benzoate and other simple arenecarboxylic acid esters have been found to undergo 2 + 2 photochemical cycloaddition at the carbonyl group to furans and certain 1,3-dienes.These additions afford mixtures of oxetanes and their 2 + 2 cycloreversion products: 4-aryl-4-alkoxy-1,3-butadienyl formates and acetates (from furan oxetanes) and dienyl aldehydes and ketones (from cyclic 1,3-dienes).
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