Chemistry of Heterocyclic Compounds p. 613 - 616 (1989)
Update date:2022-07-31
Topics:
Iovel', I. G.
Gol'dberg, Yu. Sh.
Shimanskaya, M. V.
The corresponding 2-furylhetarylmethanes were obtained by the reaction of furan, thiophene, or pyrrole with furfuryl alcohol in the presence of the strongly acidic Amberlyst 15 cation-exchange resin in the H+ form.The alkylation of furan and thiophene takes place regiospecifically in the 2 position, whereas 2-furyl-2-pyrrolyl- and 2-furyl-3-pyrrolylmethane in a ratio of 6.2:1 are formed in the case of pyrrole.
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Doi:10.1246/cl.1989.349
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