ETUDE DE L'ISOMERISATION CATALYSEE DE NITRO-5 EN NITRO-4 IMIDAZOLES

DOI: 10.1016/S0040-4039(00)82868-3

Source and publish data:

Tetrahedron Letters p. 5361 - 5364 (1988)

Update date:2022-07-30

Topics:

Authors:

Vanelle, Patrice

Jentzer, Olivier

Bahnous, Mebarek

Crozet, Michel P.

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Article abstract of DOI:10.1016/S0040-4039(00)82868-3

1-Methyl-2-substituted-5-nitroimidazoles are easily rearranged in very good yields in presence of catalytic amount of CH3I affording the corresponding 4-nitroimidazoles.The synthetic usefulness of this rearrangement and some mechanistic details are discussed.

Full text of DOI:10.1016/S0040-4039(00)82868-3

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