Tetrahedron Letters p. 5361 - 5364 (1988)
Update date:2022-07-30
Topics:
Vanelle, Patrice
Jentzer, Olivier
Bahnous, Mebarek
Crozet, Michel P.
1-Methyl-2-substituted-5-nitroimidazoles are easily rearranged in very good yields in presence of catalytic amount of CH3I affording the corresponding 4-nitroimidazoles.The synthetic usefulness of this rearrangement and some mechanistic details are discussed.
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