Total synthesis and structural revision of the presumed aeruginosins 205A and B

DOI: 10.1021/ol901702k

Source and publish data:

Organic Letters p. 4232 - 4235 (2009)

Update date:2022-08-04

Topics:

Authors:

Hanessian, Stephen

Wang, Xiaotian

Ersmark, Karolina

Del Valle, Juan R.

Klegraf, Ellen

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Article abstract of DOI:10.1021/ol901702k

A stereoselective synthesis of enantiopure aeruginosin 205B aglycon confirms the presence of a (3R,2S)-3-chloroleucine amide residue and a (6R)-hydroxy (4aR,7aS)-octahydroindole-(2S)-2-carboxamide (Choi) subunit instead of a 6-chloro-substituted core (Cco

Full text of DOI:10.1021/ol901702k

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