Journal of the American Chemical Society p. 2193 - 2204 (1989)
Update date:2022-08-04
Topics:
Danishefsky, Samuel J.
Maring, Clarence J.
A synthesis of the title system from D-galactose has been achieved.The racemic galactose 1,2,3,4-bisacetonide is expanded to a C7 heptulose, which is then extended to an undecose by a Lewis acid catalyzed cyclocondensation reaction.Racemic galactose was s
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