Stereospecific Desulfinylation of Sulfinylaziridines with Alkylmetals: A Novel Synthesis Including Asymmetric Synthesis of (Z)-N-Arylaziridines and Some Mechanistic Studies

DOI: 10.1021/jo00277a041

Source and publish data:

Journal of Organic Chemistry p. 3973 - 3978 (1989)

Update date:2022-09-26

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Authors:

Satoh, Tsuyoshi

Sato, Takahiko

Oohara, Teruhiko

Yamakawa, Koji

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Article abstract of DOI:10.1021/jo00277a041

Addition of the anion derived from 1-chloroalkyl p-tolyl sulfoxides 3 to N-arylimines 4 afforded chloro amines 5 in high yields with complete 1,2- and 1,3-asymmetric induction.Treatment of these chloro amines 5 with potassium tert-butoxide gave sulfinylaz

Full text of DOI:10.1021/jo00277a041

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