REACTIONS OF CHLOROMETHYL PHENYL SULFONE CARBANION WITH NITROBENZOPHENONES. THE VICARIOUS SUBSTITUTION OF HYDROGEN VERSUS THE DARZENS CONDENSATION

DOI: 10.1246/cl.1984.1619

Source and publish data:

Chemistry Letters p. 1619 - 1622 (1984)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Golinski, Jerzy

Baran, Janusz

Dziewonska-Baran, Danuta

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1984.1619

Carbanion of chloromethyl phenyl sulfone replaces hydrogen atoms o'- and p'- to the nitro group in o-nitrobenzophenone, whereas with p-nitrobenzophenone it enters the Darzens condensation followed by rearrangement and decarbonylation.Reaction course with

Full text of DOI:10.1246/cl.1984.1619

Products guided by the article

Product name:(4-nitrophenyl)phenyl(tetrahydropyranoxy)acetonitrile

Cas No:119657-20-4

R&D Labs maybe for 119657-20-4

Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
Yueyang Hudex Pharmaceuticals Ltd.

Contact:0730-8748800

Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone

Relevant to this article

Stereocontrolled and versatile total synthesis of bispyrrolidinoindoline diketopiperazine alkaloids: structural revision of the fungal isolate (+)-Asperdimin

Doi:10.1002/chem.200901056
(2009)
Practical, modular, and general synthesis of 3-coumaranones through gold-catalyzed intermolecular alkyne oxidation strategy

Doi:10.1002/asia.201403032
(2015)
Efficient synthesis of 5-alkoxy-(3r)-hydroxy-2,3-dihydrospiro[indene-1, 4?-piperidines]: A novel scaffold for renin inhibitors

Doi:10.1055/s-0029-1217818
(2009)
Synthesis and in Vitro Evaluation of Novel 5-Nitroindole Derivatives as c-Myc G-Quadruplex Binders with Anticancer Activity

Doi:10.1002/cmdc.202000835
(2021)
Substituted 1,4-benzoxazepines, 1,5-benzoxazocines, and N- and S-variants

Doi:10.1021/ol9023453
(2009)
Rhenium-Catalyzed Dehydrogenative Coupling of Alcohols and Amines to Afford Nitrogen-Containing Aromatics and More

Doi:10.1021/acs.orglett.9b00034
(2019)

Article Doi