REACTIONS OF CHLOROMETHYL PHENYL SULFONE CARBANION WITH NITROBENZOPHENONES. THE VICARIOUS SUBSTITUTION OF HYDROGEN VERSUS THE DARZENS CONDENSATION

DOI: 10.1246/cl.1984.1619

Source and publish data:

Chemistry Letters p. 1619 - 1622 (1984)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Golinski, Jerzy

Baran, Janusz

Dziewonska-Baran, Danuta

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1984.1619

Carbanion of chloromethyl phenyl sulfone replaces hydrogen atoms o'- and p'- to the nitro group in o-nitrobenzophenone, whereas with p-nitrobenzophenone it enters the Darzens condensation followed by rearrangement and decarbonylation.Reaction course with

Full text of DOI:10.1246/cl.1984.1619

Products guided by the article

Product name:(4-nitrophenyl)phenyl(tetrahydropyranoxy)acetonitrile

Cas No:119657-20-4

R&D Labs maybe for 119657-20-4

YORK CHEMICALS LTD

Contact:+1 (647) 918 5848

Address:2343 BRIMLEY RD., Suite 250
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Tianjin Boron PharmaTech Co.,Ltd.(expird)

Contact:86-022-59845187

Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002

Relevant to this article

Stereocontrolled and versatile total synthesis of bispyrrolidinoindoline diketopiperazine alkaloids: structural revision of the fungal isolate (+)-Asperdimin

Doi:10.1002/chem.200901056
(2009)
Practical, modular, and general synthesis of 3-coumaranones through gold-catalyzed intermolecular alkyne oxidation strategy

Doi:10.1002/asia.201403032
(2015)
Efficient synthesis of 5-alkoxy-(3r)-hydroxy-2,3-dihydrospiro[indene-1, 4?-piperidines]: A novel scaffold for renin inhibitors

Doi:10.1055/s-0029-1217818
(2009)
Synthesis and in Vitro Evaluation of Novel 5-Nitroindole Derivatives as c-Myc G-Quadruplex Binders with Anticancer Activity

Doi:10.1002/cmdc.202000835
(2021)
Substituted 1,4-benzoxazepines, 1,5-benzoxazocines, and N- and S-variants

Doi:10.1021/ol9023453
(2009)
Rhenium-Catalyzed Dehydrogenative Coupling of Alcohols and Amines to Afford Nitrogen-Containing Aromatics and More

Doi:10.1021/acs.orglett.9b00034
(2019)

Article Doi