REACTIONS OF CHLOROMETHYL PHENYL SULFONE CARBANION WITH NITROBENZOPHENONES. THE VICARIOUS SUBSTITUTION OF HYDROGEN VERSUS THE DARZENS CONDENSATION

DOI: 10.1246/cl.1984.1619

Source and publish data:

Chemistry Letters p. 1619 - 1622 (1984)

Update date:2022-08-05

Topics:

Authors:

Makosza, Mieczyslaw

Golinski, Jerzy

Baran, Janusz

Dziewonska-Baran, Danuta

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Article abstract of DOI:10.1246/cl.1984.1619

Carbanion of chloromethyl phenyl sulfone replaces hydrogen atoms o'- and p'- to the nitro group in o-nitrobenzophenone, whereas with p-nitrobenzophenone it enters the Darzens condensation followed by rearrangement and decarbonylation.Reaction course with

Full text of DOI:10.1246/cl.1984.1619

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