Cobalt-catalysed Oligomerisation of Methyl Methacrylate; Reactivation of Oligomers by Hydrocobaltation

DOI: 10.1039/c39880001179

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1179 - 1181 (1988)

Update date:2022-08-04

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Authors:

Bandaranayake, Wickramasinghe M.

Pattenden, Gerald

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Article abstract of DOI:10.1039/c39880001179

Irradiation of methyl methacrylate (MMA) in the presence of acyl- and alkyl-cobalt 'salophen' reagents leads to good yields of oligomers <(11)-(13)> by way of a novel catalytic 'hydrocobaltation-dehydrocobaltation' sequence; hydrocobaltation of the dimer (11) followed by conversion of the latter into (15) in the presence of styrene demonstrates the possibilities for 'reactivation' of oligomers of MMA for further chemical studies.

Full text of DOI:10.1039/c39880001179

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