Chemistry Letters p. 2163 - 2166 (1987)
Update date:2022-08-03
Topics:
Kusakabe, Masato
Kato, Hiroshi
Sato, Fumie
A practical method for the synthesis of several useful polyhydroxylated chiral building blocks has been developed.The key reaction is the kinetic resolution of (E)-1-trimethylsilyl-4-alkoxy-1-buten-3-ol or (E)-1-trimethylsilyl-5-alkoxy-1-penten-3-ol using the Sharpless asymmetric epoxidation reaction.
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Doi:10.1016/S0040-4039(00)80667-X
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