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| CAS No.: | 1582-09-8 |
|---|---|
| Name: | Trifluralin |
| Article Data: | 29 |
| Molecular Structure: | |
|
|
|
| Formula: | C13H16F3N3O4 |
| Molecular Weight: | 335.283 |
| Synonyms: | Crisalin;Benzenamine,2,6-dinitro-N,N-dipropyl-4- (trifluoromethyl)-;Trifloran;Crisalina;Biobarrier;Synfloran;Trifluraline;TRI-4;Tristan skuaTristar;Elancolan;Nitran K;Super-Treflan;Olitref;Agreflan;Triflurex;Trefanocide;Brassix; |
| EINECS: | 216-428-8 |
| Density: | 1.337 g/cm3 |
| Melting Point: | 48.5 °C |
| Boiling Point: | 369.1 °C at 760 mmHg |
| Flash Point: | 177 °C |
| Solubility: | <0.01 g/100 mL at 22.5 °C in water |
| Appearance: | Yellow-orange crystalline solid |
| Hazard Symbols: |
 Xi, N
|
| Risk Codes: | 36-43-50/53-20/21/22-11 |
| Safety: | 2-24-37-60-61-36-26-16 |
| Transport Information: | UN 2588 |
| PSA: | 94.88000 |
| LogP: | 5.19460 |
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- 72283-22-8
C13H17F3N3O5(1-)
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
| Conditions | Yield |
|---|---|
| With potassium hydroxide In water; dimethyl sulfoxide at 25℃; Equilibrium constant; Rate constant; var. of solvent mixture, var. KOH concentrations; |
- 79871-51-5
C17H26F3N4O4(1-)*K(1+)
A
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
B
- 109-73-9
N-butylamine
| Conditions | Yield |
|---|---|
| With water In dimethyl sulfoxide Equilibrium constant; |
- 79816-19-6
C18H26F3N4O4(1-)*K(1+)
A
- 110-89-4
piperidine
B
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
| Conditions | Yield |
|---|---|
| With water In dimethyl sulfoxide Equilibrium constant; |
- 393-75-9
4-chloro-3,5-dinitrobenzotrifluoride
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
| Conditions | Yield |
|---|---|
| In water |
- 393-75-9
4-chloro-3,5-dinitrobenzotrifluoride
- 142-84-7
di-n-propylamine
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
| Conditions | Yield |
|---|---|
| Reflux; | |
| With water; sodium hydroxide at 85 - 90℃; for 5h; Large scale; | |
| With sodium hydroxide; ascorbic acid In water at 60℃; for 2h; pH=7.5 - 8.5; Temperature; | 33.02 g |
- 110-89-4
piperidine
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
- 79816-19-6
C18H26F3N4O4(1-)*K(1+)
| Conditions | Yield |
|---|---|
| With potassium hydroxide In water; dimethyl sulfoxide Equilibrium constant; |
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
- 72283-22-8
C13H17F3N3O5(1-)
| Conditions | Yield |
|---|---|
| With potassium hydroxide In water; dimethyl sulfoxide at 25℃; Equilibrium constant; Rate constant; var.of solvent mixture, var. KOH concentrations; |
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
- 109-73-9
N-butylamine
- 79871-51-5
C17H26F3N4O4(1-)*K(1+)
| Conditions | Yield |
|---|---|
| With potassium hydroxide In water; dimethyl sulfoxide at 25℃; Rate constant; Equilibrium constant; |
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
- 16766-93-1
1-Dipropylamino-2,6-dinitro-4-tribrommethyl-benzol
| Conditions | Yield |
|---|---|
| With aluminum tri-bromide |
- 1582-09-8
2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzeneamine
A
- 2078-01-5
3-nitro-5-trifluoromethyl-1,2-phenylenediamine
B
- 445-66-9
2,6-dinitro-4-trifluoromethylaniline
C
- 2078-02-6
α,α,α-trifluoro-5-nitro-N4-propyltoluene-3,4-diamine
D
- 2077-99-8
α,α,α-trifluoro-2,6-dinitro-N-propyl-p-toluidine
E
- 69145-34-2
2,6-dinitro-4-trifluoromethyl-2',6'-dinitro-4'-<(trifluoromethyl)azo>benzene
F
- 51026-15-4
2-ethyl-7-nitro-5-(trifluoromethyl)-1H-benzimidazole
| Conditions | Yield |
|---|---|
| In methanol; water Mechanism; Irradiation; |
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Chemistry
The molecular formula of Trifluralin (1582-09-8) is C13H16F3N3O4 and its formula weight is 335.28 g/mol.
Trifluralin(1582-09-8) has the property of being dissolved in most organic solvents, xylene 58%, acetone 40% , ethanol, 7%. It is not soluble in water.
The chemical synonyms of Trifluralin (1582-09-8) are Trifurex ; TRIFLUREX ; TRIFLURALIN ; trilin 4ec ; Trifiuralin ; treflam ; TREFLAN ; TREFLAN(R). Its IUPAC Name is 2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)aniline.
The molecular structure of Trifluralin (1582-09-8):
Index of Refraction: 1.527
Density: 1.337 g/cm3
Flash Point: 177 °C
Melting point 48.5 °C
Surface Tension: 41.6 dyne/cm
Enthalpy of Vaporization: 61.58 kJ/mol
Boiling Point: 369.1 °C at 760 mmHg
Vapour Pressure: 1.21E-05 mmHg at 25 °C
Water solubility of Trifluralin (1582-09-8): <0.01 g/100 mL at 22.5 °C
Appearance of Trifluralin (1582-09-8): Yellow-orange crystalline solid
Uses
Trifluralin (1582-09-8) is used as herbicides for fruit, cotton, soybeans and other crops.
Toxicity Data With Reference
| 1. | mma-sat 1 mg/plate | ENMUDM Environmental Mutagenesis. 8 (Suppl 7)(1986),1. | ||
| 2. | mrc-asn 100 µg/plate | AISSAW Annali dellIstituto Superiore di Sanita. 18 (1982),123. | ||
| 3. | cyt-hmn:lym 2 ppm | PATHAB Pathologica. 73 (1981),707. | ||
| 4. | sce-hmn:lym 1 mg/L | BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale. 60 (1984),2149. | ||
| 5. | cyt-mus-ipr 200 mg/kg | EESADV Ecotoxicology and Environmental Safety. 4 (1980),263. | ||
| 6. | orl-mus TDLo:10 mg/kg (6-15D preg):TER | TJADAB Teratology, A Journal of Abnormal Development. 15 (1977),15A. | ||
| 7. | ipr-mus TDLo:200 mg/kg (1D male):REP | EESADV Ecotoxicology and Environmental Safety. 4 (1980),263. | ||
| 8. | orl-mus TDLo:180 g/kg/78W-C:CAR | NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-34 ,1978. | ||
| 9. | ipr-mus TDLo:2600 µg/kg/39D-I:ETA | PATHAB Pathologica. 73 (1981),707. | ||
| 10. | orl-mus TD:340 g/kg/78W-C:CAR | NCITR* National Cancer Institute Carcinogenesis Technical |
Consensus Reports
NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-34 ,1978. ; No Evidence: rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-34 ,1978. . EPA Genetic Toxicology Program. Community Right-To-Know List.
Safety Profile
Moderately toxic by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of F− and NOx. See also FLUORIDES.
Hazard Codes: 
Xi,
N,
Xn,
F
Risk Statements: 36-43-50/53-20/21/22-11
R36:Irritating to eyes.
R43:May cause sensitization by skin contact.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R11:Highly flammable.
Safety Statements: 2-24-37-60-61-36-26-16
S2:Keep out of the reach of children.
S24:Avoid contact with skin.
S37:Wear suitable gloves.
S60:This material and its container must be disposed of as hazardous waste.
S36:Wear suitable protective clothing.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S16:Keep away from sources of ignition.
RIDADR: UN 2588
RTECS: XU9275000
Hazardous Substances Data: 1582-09-8(Hazardous Substances Data)