Journal of the American Chemical Society p. 4852 - 4856 (1989)
Update date:2022-07-31
Topics:
Winkler, Jeffrey D.
Hershberger, Paul M.
The first synthesis of (-)-perhydrohistrionicotoxin, 2, which proceeds without recourse to resolution of synthetic intermediates is reported.The absolute stereochemistry is derived from L-glutamic acid, and the key step, in which the critical relative ste
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