A HIGHLY PRACTICAL SYNTHESIS OF CHIRAL (E)-1-TRIMETHYLSILYL-1-ALKEN-3,4-DIOLS VIA THE SHARPLESS ASYMMETRIC EPOXIDATION OF 1,5-BIS(TRIMETHYLSILYL)-1,4-PENTADIEN-3-OL. FORMAL TOTAL SYNTHESIS OF LIPOXIN B

DOI: 10.1016/S0040-4039(00)82330-8

Source and publish data:

Tetrahedron Letters p. 6297 - 6300 (1988)

Update date:2022-08-02

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Authors:

Kobayashi, Yuichi

Kato, Norihiro

Shimazaki, Toshiyuki

Sato, Fumie

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Article abstract of DOI:10.1016/S0040-4039(00)82330-8

The Sharpless asymmetric epoxidation of the alcohol 4 proceeds with an extremely high efficiency to afford the epoxide 5 from which the title chiral alcohol 2 is synthesized in good overall yield.By using the alcohol 2, the Nicolaou's lipoxin B intermedia

Full text of DOI:10.1016/S0040-4039(00)82330-8

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