Synthetic Studies on Germacranolides: Synthesis of Optically Active 3-Benzoyloxy-6-oxo-13-nor-12,8-heliangolide

DOI: 10.1246/bcsj.61.1207

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1207 - 1212 (1988)

Update date:2022-08-05

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Authors:

Utagawa, Akiko

Hirota, Hiroshi

Ohno, Shigeru

Takahashi, Takeyoshi

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Article abstract of DOI:10.1246/bcsj.61.1207

Optically active (3R,7R,8R,1(10)E,4Z)-3-benzoyloxy-6-oxo-13-nor-1(10),4-germacradieno-12,8-lactone, a key synthetic intermediate for naturally occurring hiyodorilactone A, was prepared from (-)-carvone.

Full text of DOI:10.1246/bcsj.61.1207

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Product name:(3R,1⁽¹⁰⁾E,4Z)-3-benzoyloxy-11.12,13-trinor-1⁽¹⁰⁾,4-germacradiene-6,8-dione

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