134. Catalytic Intramolecular Palladium-Ene Reactions

DOI: 10.1002/hlca.19870700604

Source and publish data:

Helvetica Chimica Acta p. 1477 - 1481 (1987)

Update date:2022-08-04

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Authors:

Oppolzer, Wolfgang

Gaudin, Jean-Marc

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Article abstract of DOI:10.1002/hlca.19870700604

Pd(dba)2/PPh3- or Pd(PPh3)4-catalyzed cyclizations of acetoxy-dienes 2 -> 3 and 10 -> 11 gave 1-vinyl-2-methylidene-substituted cyclopentanes and cyclohexanes in high yield, consistent with a palladium-ene/β-elimination mechani

Full text of DOI:10.1002/hlca.19870700604

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