Complications in the Reactions of Tris(thio)methyl-lithium Derivatives with δ-Valerolactone

DOI: 10.1039/c39890000177

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 177 - 178 (1989)

Update date:2022-07-29

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Authors:

Yates, Peter

Krepinsky, Jiri J.

Seif-el-nasr, Azza

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Article abstract of DOI:10.1039/c39890000177

Reaction of tris(methylthio)methyl-lithium, tris(phenylthio)methyl-lithium, and 2-lithio-2-(methylthio)-1,3-dithiane with δ-valerolactone gives, respectively, 2tetrahydropyran-2-ol, phenyl tetrahydro-2-oxo-pyran-3-thiocarboxylate, and both 2-<2-(1,3-dithianyl)>tetrahydropyran-2-ol and 2-<2-(1,3-dithianyl)>tetrahydro-2-(methylthio)pyran-2-ol.

Full text of DOI:10.1039/c39890000177

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