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Figure 3. Temperature dependences of the magnetic susceptibility vm and
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Acknowledgments
This work was supported by Precursory Research for Embryonic
Science and Technology (PRESTO), Japan Science and Technology
(JST) (D.J.) and a grant-in-aid for scientific research from Japan
Society for the Promotion of Science (Nos. 18850025 and
20750118; T.I.).
corresponding porphyrinogen, whereas that for 2 substitutes the
position) of the alkyl-tethered pyrrole. The difference in the reactivity between
the
- and the a0-carbons of the b-mono-substituted pyrrole rings may cause
a-position (2-
Supplementary data
a
the excessive yield of 2 over 1 under the condition.
Supplementary data associated with this article can be found, in
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References and notes
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Figure 1, the presence of H+ promotes the scrambling reaction. Probably,
because 1,2-dichloroethane contains a little amount of acid and it may cause a
worse isomeric ratio 2/1 than EtOH.
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17. A referee suggested the possibility that the precipitate of the short rod-like
structure is crystallographically a chiral twin and that of the helical ribbon
structure is chiral. At present, however, we have no evidence to support the
possibility and thus we just mention the possibility here.