Journal of Organic Chemistry p. 3521 - 3523 (1989)
Update date:2022-08-04
Topics:
Swanson, Douglas R.
Rousset, Christophe J.
Negishi, Ei-ichi
Takahashi, Tamotsu
Seki, Takashi
et al.
The reaction of Cp2Zr(CH2CH2R1)2 with a monosubstituted terminal alkene (H2C=CHR2) can produce, in a highly regio- and diastereoselective manner, zirconacyclopentane derivatives; the trans-3,4-disubstituted derivatives may be formed to the extents of >98percent in cases where both R1 and R2 are alkyl, while the trans-2-aryl-4-alkyl derivatives may be formed to the extents of >98percent in the coupling between a monoalkyl-substituted olefin and styrene or its derivative.
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