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584-09-8

Basic Information
CAS No.: 584-09-8
Name: Carbonic acid, rubidiumsalt (1:2)
Molecular Structure:
Molecular Structure of 584-09-8 (Carbonic acid, rubidiumsalt (1:2))
Formula: Rb2CO3
Molecular Weight: 230.95
Synonyms: Carbonicacid, dirubidium salt (8CI,9CI);Rubidium carbonate (6CI,7CI);Dirubidiumcarbonate;Dirubidium monocarbonate;Rubidium carbonate (Rb2CO3);
EINECS: 209-530-9
Density: N/A
Melting Point: 837 °C
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: soluble in water
Appearance: white powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-37/39
Transport Information: N/A
PSA: 63.19000
LogP: -2.44700
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    Rubidium carbonate

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    Rubidium Carbonate

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Chemistry

Molecular Formula: CO3Rb2
Molar mass: 230.9445 g/mol
EINECS: 209-530-9
Flash Point: 169.8 °C
Boiling Point: 333.6 °C at 760 mmHg
Vapour Pressure: 2.58E-05 mmHg at 25°C
Melting point: 837 °C
Storage temp: -20°C
Water solubility: Soluble
Sensitive: Hygroscopic
Appearance: White powder
Product categories: Chemical Synthesis;Rubidium Salts;Synthetic Reagents;Inorganic BasesMetal and Ceramic Science
Structure of Rubidium carbonate (584-09-8):
              
H-Bond Donor: 0
H-Bond Acceptor: 3
Systematic Name: Rubidium(+1) cation carbonate 
SMILES: [Rb+].[Rb+].[O-]C([O-])=O 
InChI: InChI=1/CH2O3.2Rb/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 
InChIKey: WPFGFHJALYCVMO-NUQVWONBAM 
Std. InChI: InChI=1S/CH2O3.2Rb/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 
Std. InChIKey: WPFGFHJALYCVMO-UHFFFAOYSA-L

Uses

 Rubidium carbonate (584-09-8) is used as a part of a catalyst for preparing short-chain alcohols from feed gas, and also used in some kinds of glass-making by enhancing stability and durability as well as reducing its conductivity.

Production

 Rubidium carbonate (584-09-8) can be prepared by adding Ammonium carbonate to Rubidium hydroxide.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intraperitoneal 450mg/kg (450mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 31(9), Pg. 55, 1987.
rat LD50 oral 2625mg/kg (2625mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 31(9), Pg. 55

Carcinogenicity of Rubidium carbonate (584-09-8) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.You can see actual entry in RTECS for complete information.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of Rb.
 

Hazard Codes: Xi
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection

Specification

 Rubidium carbonate (584-09-8) is a convenient compound of rubidium, and also can be called Dirubidium monocarbonate ; Dirubidium carbonate ; Carbonic acid dirubidium salt .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.Notes to physician: Treat supportively and symptomatically.
In addition, Rubidium carbonate (584-09-8) is moisture sensitive, and can absorb moisture or water.It is not compatible with strong oxidizing agents, and you must not take it with dust generation and incompatible materials.And also prevent it to broken down into hazardous decomposition products: carbon dioxide, carbon monoxide.