Tetrahedron Letters p. 4773 - 4776 (1988)
Update date:2022-08-04
Topics:
Isobe, Minoru
Obeyama, Junko
Funabashi, Yasunori
Goto, Toshio
A new asymmetric synthesis is reported that includes carbon-carbon bond formation based upon heteroconjugate addition with Eliel's 1R-(+)-camphor derivative as a template.This method showed high enantiomeric excess under chelation control affected by the solvent polarity and by the salt present in the reaction media. (+)-citronellal was synthesized as a proof of this method.
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