CYCLIC CARBONYL YLIDE FORMATION FROM THE RHODIUM (II) ACETATE CATALYZED REACTION OF 1-DIAZOALKANEDIONES

DOI: 10.1016/S0040-4039(00)95185-2

Source and publish data:

Tetrahedron Letters p. 301 - 304 (1989)

Update date:2022-08-03

Topics:

Authors:

Padwa, Albert

Chinn, Richard L.

Hornblucke, Susan F.

Zhi, Lin

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Article abstract of DOI:10.1016/S0040-4039(00)95185-2

Treatment of 1-diazoalkanediones with rhodium (II) acetate results in cyclization of the intermediate rhodium carbenoid to give a cyclic carbonyl ylide which readily undergoes bimolecular dipolar cycloaddition with various dipolarophiles.

Full text of DOI:10.1016/S0040-4039(00)95185-2

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