Novel preparation of polymer-supported iodobenzene and its synthetic utility as a recyclable reagent with m-chloroperbenzoic acid

Article abstract of DOI:10.1055/s-0029-1218795

Three novel polymer-supported iodobenzene compounds A₀, A ₆, and A₁₀ were prepared from the reaction of commercially available cross-linked poly(p-chloromethyl)styrene with m-iodobenzylalcohol, 6-(m-iodobenzyloxy)-1-hexanol, and 10-(m-iodobenzyloxy)-1-decanol. Their catalytic reactivity and reusability for the oxidative α-tosyloxylation of ketones and the cyclization of N-methoxy-2-arylethanesulfonamides in the presence of m-chloroperbenzoic acid (mCPBA) were confirmed to provide -tosyloxyketones and N-methoxy-3,4-dihydro-2,1-benzothiazine-2,2-dioxides, respectively, in good yields. Georg Thieme Verlag Stuttgart · New York.