Angewandte Chemie - International Edition p. 5757 - 5761 (2010)
Update date:2022-08-04
Topics:
Huang, David S.
Hartwig, John F.
(Figure Presented) Smarty cat: A method for the palladiumcatalyzed γ-arylation of α,β-unsaturated esters via silyl ketene acetals in the absence of fluoride has been developed. The coupling proceeds with electron-rich and electron-poor aryl bromides and vinyl bromides in high yields with a high tolerance for other functional groups.
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