Novel S-N Ring Contractions using the 4-Phenyl-1,2,3,5-dithiadiazole Dimer, the Synthesis and X-Ray Crystal Structures of , , and Cl, and an Ab Initio Molecular-orbital Study of the Bonding in <S3

DOI: 10.1039/DT9900002793

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2793 - 2802 (1990)

Update date:2022-08-04

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Authors:

Banister, Arthur J.

Hansford, Michael I.

Hauptman, Zdenek V.

Luke, Anthony W.

Wait, Simon T.

et al. et al.

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Article abstract of DOI:10.1039/DT9900002793

When the 4-phenyl-1,2,3,5-dithiadiazole dimer (1) dehalogenates Cl a novel ring contraction occurs producing <(PhCN2S2)2Cl>, (2), in acetonitrile, and a mixture of (2) and , (3), in pentane.The salt Cl is also dehalogenate

Full text of DOI:10.1039/DT9900002793

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