Palladium-catalyzed, ligand-free SN2’ substitution reactions of organoaluminum with propargyl acetates for the synthesis of multi-substituted allenes

DOI: 10.1016/j.jorganchem.2018.06.020

Source and publish data:

Journal of Organometallic Chemistry p. 68 - 75 (2018)

Update date:2022-07-30

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Authors:

Shao, Xuebei

Wen, Chang

Zhang, Gang

Cao, Kangping

Wu, Ling

Li, Qinghan

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Article abstract of DOI:10.1016/j.jorganchem.2018.06.020

We describe a convenient method for the synthesis of multi-substituted allenes from S_N2′ substitution reactions organoaluminum with propargyl acetates: The S_N2′ substitution reaction of organoaluminum (0.4 mmol) with propargyl acetat

Full text of DOI:10.1016/j.jorganchem.2018.06.020

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