Diphenylphosphinoyl-Substituted Ylides. 1. Thermal 1,3-Dipolar Cycloaddition of α-(Diphenylphosphinoyl)glycine Ester Imines. Dipole Formation as the Rate-Determining Step.

DOI: 10.1021/jo00300a022

Source and publish data:

Journal of Organic Chemistry p. 4063 - 4069 (1990)

Update date:2022-08-05

Topics:

Authors:

Es, J. J. G. Steven van

Jaarsveld, Korien

Gen, Arne van der

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Article abstract of DOI:10.1021/jo00300a022

The thermal 1,3-dipolar cycloaddition of N-benzylidene-α-(diphenylphosphinoyl)glycine esters 4 to N-phenylmaleimide is described.With this reactive dipolarophile, dipole formation is the rate-determining step.Addition to less reactive dipolarophiles is co

Full text of DOI:10.1021/jo00300a022

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