Synthesis of 1,3-Dithiol-2-thione Derivatives by Phase Transfer Dithiocarboxylation of CH-Acidic O-Alkyl Dithiocarbonates

DOI: 10.1007/BF00811127

Source and publish data:

Monatshefte fur Chemie p. 879 - 890 (1989)

Update date:2022-08-04

Topics:

Authors:

Doelling, Wolfgang

Vogt, Almut

Augustin, Manfred

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00811127

CH-Acidic O-alkyl dithiocarbonates 1 react with carbon disulfide in a one-pot synthesis under basic conditions (NaH in DMF or phase transfer conditions) and S-alkylation to novel 1,3-dithiole-2-thiones 3-6.The structure of these compounds and supporting n.m.r., ir and mass spectra are discussed. - Keywords: 1,3-Dithiole-2-thiones; Dithiocarboxylation; O-Alkyl dithiocarbonates; Cyclocondensation; Phase transfer dithiocarboxylation; Carbon disulfide.

Full text of DOI:10.1007/BF00811127

Products guided by the article

Product name:5-phenacylthio-2-thioxo-1,3-dithiol-4-carbonsaueremethylester

Cas No:127252-33-9

R&D Labs maybe for 127252-33-9

zhangjiagang bonded areas banggao co;ltd

website:http://www.shunchangchem.com

Contact:0086-13921972933

Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
WuHan rongfashun BioChemical co., LTD

Contact:02788866139

Address:No.95 LuoYu Road,Wuhan

Relevant to this article

New glucocerebrosidase inhibitors by exploration of chemical diversity of N -substituted aminocyclitols using click chemistry and in situ screening

Doi:10.1021/jm101204u
(2011)
Synthesis of chiral 1-substituted tetrahydroisoquinolines by the intramolecular 1,3-chirality transfer reaction catalyzed by Bi(OTf)₃

Doi:10.1021/jo102452d
(2011)
Ammonium oxalate as an efficient catalyst for one-pot synthesis of tetrahydrobenzo [a]xanthen-11-one derivatives under solvent-free conditions

Doi:10.1080/15533174.2012.754767
(2013)
Synthesis and thermal reactivity of 3-benzyl-7-trifluoromethyl-1H,3H- pyrrolo[1,2-c]thiazole-2,2-dioxide

Doi:10.1016/j.tet.2013.03.017
(2013)
Achieving improved permeability by hydrogen bond donor modulation in a series of MGAT2 inhibitors

Doi:10.1039/c3md00156c
(2013)
Nucleophile-dependent regioselective reaction of (S)-4-benzyl-2- fluoroalkyl-1,3-oxazolines

Doi:10.1021/jo400073d
(2013)

Article Doi