Asymmetric Diels-Alder Reactions of Chiral Isoprenyl Ethers with Reactive Dienophiles

DOI: 10.1055/s-1989-27405

Source and publish data:

Synthesis p. 836 - 843 (1989)

Update date:2022-08-05

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Authors:

Thiem, Roland

Rotscheidt, Klaus

Breitmaier, Eberhard

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Article abstract of DOI:10.1055/s-1989-27405

The chiral alcohols 2 react with 3-ethoxy-2-methylacrolein (1) to yield chiral 3-alkoxy-2-methylacroleins 3, which are transformed to the chiral isoprenyl ethers 5 by Wittig methylenation in good yields. 1,3-Dienes 5 undergo <4+2> cycloadditions with reac

Full text of DOI:10.1055/s-1989-27405

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