REACTION OF HYDROXYLAMINE WITH BENZENESULFONYL CHLORIDE. X-RAY CRYSTAL STRUCTURE OF PILOTY'S ACID AND OTHER BENZENESULFONYLHYDROXYLAMINES.

DOI: 10.1016/S0040-4020(01)85786-0

Source and publish data:

Tetrahedron p. 7695 - 7708 (1989)

Update date:2022-09-26

Topics:

Authors:

Scholz, John N.

Engel, Paul S.

Glidewell, Christopher

Whitmire, Kenton H.

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Article abstract of DOI:10.1016/S0040-4020(01)85786-0

The X-ray crystal structures of the four stable phenylhydroxylamines (PhSO2NHOH, (PhSO2)2NOH, PhSO2NHOSO2Ph, (PhSO2)2NOSO2Ph), and of PhSO3^-⁺H3NHNSO2Ph are presented.The last of these is a by-product obtained during the isolation of PhSO2NHOH (Piloty's Acid).The formation of and the bonding in these molecules are discussed.

Full text of DOI:10.1016/S0040-4020(01)85786-0

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