Access to ultra-high-molecular weight poly(ethylene) and activity boost in the presence of cyclopentene with group 4 bis-amido complexes

DOI: 10.1002/cplu.201300378

Source and publish data:

ChemPlusChem p. 151 - 162 (2014)

Update date:2022-08-03

Topics:

Authors:

Narayana, Gurram Venkata

Xu, Guangjuan

Wang, Dongren

Frey, Wolfgang

Buchmeiser, Michael R.

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Article abstract of DOI:10.1002/cplu.201300378

ZrIV complexes of the type [Me₂Si{(NR)(6-{2-(diethylboryl) phenyl} pyridyl-2-yl-N)}ZrCl2 thf] (R=tBu (4), adamantyl (7a); thf= tetrahydrofuran), [Me₂Si{(NAd)(6-{2-(diphenylboryl)phenyl}pyridyl- 2-yl-N)}ZrCl2] (Ad=adamantyl (7b)), the

Full text of DOI:10.1002/cplu.201300378

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