Tandem Cyclization-Cycloaddition Reaction of Rhodium Carbenoids. Studies Dealing with Intramolecular Cycloadditions

DOI: 10.1021/jo00047a032

Source and publish data:

Journal of Organic Chemistry p. 5747 - 5757 (1992)

Update date:2022-08-03

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Authors:

Padwa, Albert

Hornbuckle, Susan F.

Fryxell, Glen E.

Zhang, Zhijia J.

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Article abstract of DOI:10.1021/jo00047a032

A series of 5-alkenyl-1-diazo-2,5-pentanediones, when treated with a catalytic quantity of rhodium(II) acetate, were found to give cycloadducts derived from the intramolecular trapping of a carbonyl ylide intermediate.Tethers of three or four methylenes r

Full text of DOI:10.1021/jo00047a032

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