Evidence for a bis(alkylidene)silacyclopropane intermediate in the platinum-mediated formation of a silacyclobutene

DOI: 10.1021/ja00176a023

Source and publish data:

Journal of the American Chemical Society p. 7229 - 7233 (1990)

Update date:2022-07-31

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Authors:

Dema, Anne C.

Lukehart

McPhail, Andrew T.

McPhail, Donald R.

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Article abstract of DOI:10.1021/ja00176a023

When Ph₂Si(C≡CCMe₃)₂ is treated with a cationic Pt-H reagent, a 4-alkylidene-1-silacyclobutenyl ring system is formed. Evidence for the presence of two intermediates in this reaction sequence is obtained by using selective

Full text of DOI:10.1021/ja00176a023

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