Synthesis of 2-deoxy-β-C-pyranosides by diastereoselective hydrogen atom transfer

DOI: 10.1016/S0040-4039(00)98814-2

Source and publish data:

Tetrahedron Letters p. 1897 - 1900 (1990)

Update date:2022-08-02

Topics:

Authors:

Crich, David

Lim, Linda B. L.

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Article abstract of DOI:10.1016/S0040-4039(00)98814-2

2-Deoxy-β-C-pyranosides are synthesized by sequential treatment of methyl 3-deoxy-2-phenylsulphonyl-4,5,7-tri-O-benzyl-D-arabino-heptulosonate with lithium naphthalenide and an alkyl halide followed by saponification and reductive decar□ylation. (Chemical

Full text of DOI:10.1016/S0040-4039(00)98814-2

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Product name:methyl (2-benzyl-4,5,7-tri-O-benzyl-2,3-dideoxy)-β-D-arabino-hept-2-ulopyranosonate

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