Pentacovalent phosphorus-containing models of P(V) H2O- or enzyme-cAMP adducts. Nonchair conformations of the phosphorus-containing rings as determined by 1 H NMR spectroscopy and X-ray crystallography

DOI: 10.1021/ja00177a002

Source and publish data:

Journal of the American Chemical Society p. 7451 - 7461 (1990)

Update date:2022-09-26

Topics: X-ray crystallography H₂O Phosphorus-containing P(V)

Authors:

Yu, Jaehoon H.

Arif, Atta M.

Bentrude, Wesley G.

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Article abstract of DOI:10.1021/ja00177a002

A series of pentacovalent phosphorus-containing, P(V), molecules (3-6), designed as models of P(V) H₂O-cAMP or enzyme-cAMP adducts (or transition states) were prepared and studied by NMR (3-6) and X-ray crystallography (6). The preparation of 3

Full text of DOI:10.1021/ja00177a002

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