Synthesis of Enantiomerically Pure 1-Methyl-2-alkenyl N,N-Diisopropylcarbamates from (S)- or (R)-Lactates

DOI: 10.1055/s-1990-26855

Source and publish data:

Synthesis p. 291 - 294 (1990)

Update date:2022-08-04

Topics:

Authors:

Schwark, Jan-Robert

Hoppe, Dieter

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Article abstract of DOI:10.1055/s-1990-26855

Starting from enantiomerically pure alkyl (S)- or (R)-lactates the title compounds are obtained by Wittig olefination of 2-(N,N-diisopropylcarbamoyloxy)propanal.The reaction sequence proceeds without racemization.

Full text of DOI:10.1055/s-1990-26855

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Product name:Diisopropyl-carbamic acid (Z)-(S)-1-methyl-3-phenyl-allyl ester

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