TOTAL SYNTHESIS OF GALANTIN I. REVISION OF THE ORIGINAL STRUCTURE

Article abstract of DOI:10.1016/S0040-4039(00)94727-0

The proposed structure of galantin I, isolated as a mixture of homologs (1a/1b = 9/1), was shown to be incorrect by total synthesis and was revised twice to finally give 5a and 5c, respectively, by total synthesis.