Chemistry Letters p. 1671 - 1674 (1990)
Update date:2022-08-05
Topics:
Abe, Taro
Aso, Yoshio
Otsubo, Tetsuo
Ogura, Fumio
Diphenyl ditelluride rapidly reacted with trialkylboranes in the presence of oxygen to give alkyl phenyl tellurides in high yields.The facile rection proceeds via a free-radical mechanism induced by a stoichiometric amount of oxygen.A combination of this transmetallation with hydroboration provides an alternative method for hydrotelluration of olefins.
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