Total synthesis of (-)-anamarine

DOI: 10.1021/jo2010389

Source and publish data:

Journal of Organic Chemistry p. 6889 - 6893 (2011)

Update date:2022-08-04

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Authors:

Prasad, Kavirayani R.

Penchalaiah, Kamala

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Article abstract of DOI:10.1021/jo2010389

Total synthesis of polyhydroxy δ-pyranone natural product (-)-anamarine is accomplished from d-(-)-tartaric acid. The main feature of the synthesis is the utility of hitherto unexplored β-keto phosphonate derived from tartaric acid amide and further elaboration involving stereoselective reduction.

Full text of DOI:10.1021/jo2010389

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