Tetrahedron Letters p. 6725 - 6728 (1990)
Update date:2022-07-29
Topics:
Bonar-Law
Davis
Dorgan
Reetz
Wehrsig
The "benzostabase" (BSB) protecting group has been applied to primary aliphatic amines. It can be introduced via a dehydrogenative silylation employing an air- and moisture-stable reagent, and is appreciably more acid-stable than the related "stabase" group. BSB protection has been used in a stereoselective synthesis of amino-alcohols involving the addition of organometallic reagents to protected amino-aldehydes under "non-chelation control".
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Doi:10.1007/BF00768378
(1990)Doi:10.1016/S0040-4039(00)97193-4
(1990)Doi:10.1055/s-0030-1260049
(2011)Doi:10.1002/chem.201101703
(2012)Doi:10.1007/s11172-015-0964-9
(2015)Doi:10.1039/P29800001606
(1980)