Stereoselective Synthesis of Terminal 1,3-Butadienes by the Condensation Reaction of Aldehydes and Ketones with the γ-Trimethylsilyl-Substituted Allylboranes

DOI: 10.1021/jo00005a045

Source and publish data:

Journal of Organic Chemistry p. 1914 - 1922 (1991)

Update date:2022-08-05

Topics:

Authors:

Wang, Kung K.

Liu, Chin

Gu, Yu Gui

Burnett, Friedrich N.

Sattsangi, Prem D.

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Article abstract of DOI:10.1021/jo00005a045

Allylboranes 7-12, readily prepared from allenylsilanes 1-6 by hydroboration with 9-borabicyclo<3.3.1>nonane, smoothly condense with aldehydes and ketones to afford, after basic or acidic workup to promote the Peterson olefination reaction, a variety of t

Full text of DOI:10.1021/jo00005a045

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