Stereoselective Synthesis of Terminal 1,3-Butadienes by the Condensation Reaction of Aldehydes and Ketones with the γ-Trimethylsilyl-Substituted Allylboranes

DOI: 10.1021/jo00005a045

Source and publish data:

Journal of Organic Chemistry p. 1914 - 1922 (1991)

Update date:2022-08-05

Topics:

Authors:

Wang, Kung K.

Liu, Chin

Gu, Yu Gui

Burnett, Friedrich N.

Sattsangi, Prem D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00005a045

Allylboranes 7-12, readily prepared from allenylsilanes 1-6 by hydroboration with 9-borabicyclo<3.3.1>nonane, smoothly condense with aldehydes and ketones to afford, after basic or acidic workup to promote the Peterson olefination reaction, a variety of t

Full text of DOI:10.1021/jo00005a045

Products guided by the article

Product name:2-Methyl-1,1-pentamethylene-1,3-butadiene

Cas No:132440-30-3

R&D Labs maybe for 132440-30-3

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Weifang Yukai Chemical Co.,Ltd.

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Xi'an Terra Biochem Co. Ltd.

Contact:0086-29-88315623

Address:S711, Innovation Bldg No.25 Gaoxin 1st Rd, Xian P.R of China 710075

Relevant to this article

Organometallic iridium(III) cyclopentadienyl anticancer complexes containing C,N-Chelating ligands

Doi:10.1021/om2005468
(2011)
Net heterolytic cleavage of B-H and B-B bonds across the N-Pd bond in a cationic (PNP)Pd fragment

Doi:10.1021/ic2001283
(2011)
Synthesis of 1,2,5- and 1,2,3,5-substituted pyrroles from substituted aziridines via Ag(I)-catalyzed intramolecular cyclization

Doi:10.1016/j.tet.2011.02.072
(2011)
SAR by interligand nuclear overhauser effects (ILOEs) based discovery of acylsulfonamide compounds active against Bcl-x_L and Mcl-1

Doi:10.1021/jm200826s
(2011)
Racemic and optically active 2-chloroethylcarbamoyl derivatives of 7,8-dimethoxy-1-phenyl-2,3,4,5-tetrahydro-1H-3-benzazepine: A new structural type of DA, NE, and 5-HT Uptake Inhibitors

Doi:10.1002/ardp.19903231003
(1990)
Synthetic routes to, transformations of, and rather surprising stabilities of (N-Methyl-N-phenylcarbamoyl)sulfenyl Chloride, ((N-Methyl-N-phenylcarbamoyl) dithio)carbonyl chloride, and related compounds

Doi:10.1021/jo201329n
(2011)

Article Doi