Journal of the Chemical Society. Perkin transactions I p. 211 - 214 (1991)
Update date:2022-08-03
Topics:
Hashidoko, Yasuyuki
Tahara, Satoshi
Mizutani, Junya
In the autoxidation of (7R,10R)-carota-1,4-dien-14-al 1, which is a precursor of an antifungal compound rugosal A 2, in Rosa rugosa leaves, an intermediate possessing a 1,5-endoperoxy-2-hydroperoxy system 4 was isolated as a major product.The structures of compound 4 and other by-products including rugosal A 2 and rugosic acid A 3 were determined.These autoxidation products indicated the conversion pathway of compound 1 into rugosal A 2, similar to the radical reaction pathway in the autoxidation of polyunsaturated fatty acids.
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