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4075-81-4

Basic Information
CAS No.: 4075-81-4
Name: Calcium Propionate
Article Data: 8
Molecular Structure:
Molecular Structure of 4075-81-4 (Calcium Propionate)
Formula: 2(C3H6O2).Ca
Molecular Weight: 186.221
Synonyms: Propanoicacid, calcium salt (9CI);Propionic acid, calcium salt (8CI);Bioban-C;Calcium propanoate;Calcium propionate;Calcium dipropionate;
EINECS: 223-795-8
Density: 1.41[at 20℃]
Melting Point: 300 °C
Boiling Point: 141.7 °C at 760 mmHg
Flash Point: 57.7 °C
Solubility: 1 g/10 mL in water
Appearance: white powder
Hazard Symbols: 36/37/38:;
Risk Codes: 36/37/38
Safety: 24/25
PSA: 52.60000
LogP: 0.80780
Synthetic route
107-12-0

propiononitrile

A

4075-81-4

calcium propionate

B

79-05-0

Propionamid

Conditions
ConditionsYield
With calcium hydroxide; water at 160 - 200℃; under 516.802 - 13445.8 Torr; for 2.66 - 12.33h; Conversion of starting material;A 24.2%
B 0.0114%
With calcium hydroxide; water at 160 - 200℃; under 7328 - 14206.3 Torr; for 2 - 12.33h; Product distribution / selectivity;
802294-64-0

propionic acid

4075-81-4

calcium propionate

Conditions
ConditionsYield
With calcium oxide at 180℃; under 3750.38 Torr; Reagent/catalyst; Pressure; Temperature; Autoclave; Large scale;52.1 kg
802294-64-0

propionic acid

calcium oxide

4075-81-4

calcium propionate

Conditions
ConditionsYield
at 26 - 170℃; for 0.3h; Product distribution / selectivity;
In water at 125℃; for 0.183333h; Product distribution / selectivity;
802294-64-0

propionic acid

calcium carbonate

calcium oxide

4075-81-4

calcium propionate

Conditions
ConditionsYield
In water at 115℃; for 0.25h; Product distribution / selectivity;
802294-64-0

propionic acid

79-05-0

Propionamid

4075-81-4

calcium propionate

Conditions
ConditionsYield
Stage #1: Propionamid With calcium hydroxide; water at 60 - 103℃;
Stage #2: propionic acid In water pH=8.1;
102-82-9

tributyl-amine

124-38-9

carbon dioxide

4075-81-4

calcium propionate

A

75775-31-4

propanoic acid tributylamine salt

B

calcium carbonate

Conditions
ConditionsYield
In water for 0.5h; Product distribution / selectivity;A n/a
B 90.8%
4075-81-4

calcium propionate

541-15-1

L-carnitine

L-carnitine calcium propionate

Conditions
ConditionsYield
In water for 0.25h;90%
4075-81-4

calcium propionate

24634-61-5

potassium sorbate

calcium propionate sorbate

Conditions
ConditionsYield
In water at 25℃; for 0.0333333h;75%

manganese(II) perchlorate hexahydrate

1196-29-8

2-hydroxyacetophenoneoxime

4075-81-4

calcium propionate

75-05-8

acetonitrile

A

Mn4(2-hydroxyphenylethanone oxime(-2H))4(2-hydroxyphenylethanone oxime(-1H))4*3.5MeCN

B

poly[[Mn(III)6Ca2O2(2-hydroxyphenylethanone oxime(-2H))6(propionato)6(H2O)2]*2MeCN*0.95H2O]

Conditions
ConditionsYield
In acetonitrile Mn(ClO4)2*6H2O, oxime ligand, Ca-propionate (1:1:1 mol) stirred in MeCN overnight; filtered; crystd. from filtrate over few ds; XRD;A n/a
B 40%
532-32-1

sodium benzoate

4075-81-4

calcium propionate

C3H5O2(1-)*C7H5O2(1-)*Ca(2+)

Conditions
ConditionsYield
In water at 25℃; for 0.0333333h;
Raw Materials
107-12-0
79-05-0
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    Product Name: Calcium dipropionate Alias: Calcium propionate Molecular formula: C6H10CaO4 Molecular weight: 186.22 CAS: 4075-81-4 EINECS: 223-795-8 Description: white powder or monoclinic crystal. The solubility in 100 mg of water is: 20 °

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Chemistry

Molecular Formula: Ca(C2H5COO)2
Molecular Weight: 186.22
EINECS: 223-795-8
Flash Point: 57.7 °C
Enthalpy of Vaporization: 40.08 kJ/mol
Boiling Point: 141.7 °C at 760 mmHg
Vapour Pressure: 4.23 mmHg at 25 °C
Melting point: 300 °C
Water solubility: 1 g/10 mL
Appearance: White powder
Structure of Calcium propionate (CAS NO.4075-81-4):
                 
IUPAC Name: Calcium propanoate
Canonical SMILES: CCC(=O)[O-].CCC(=O)[O-].[Ca+2]
InChI: InChI=1S/2C3H6O2.Ca/c2*1-2-3(4)5;/h2*2H2,1H3,(H,4,5);/q;;+2/p-2
InChIKey: BCZXFFBUYPCTSJ-UHFFFAOYSA-L
Product Category of Calcium propionate (CAS NO.4075-81-4): Ca (Calcium) Compounds;Classes of Metal Compounds;Typical Metal Compounds;Food & Flavor Additives

Uses

 Calcium propionate (CAS NO.4075-81-4) is used as a preservative in a wide variety of products, including but not limited to bread, other baked goods, processed meat, whey, and other dairy products. In agriculture, it is used to prevent milk fever in cows and as a feed supplement  propionates prevent microbes from producing the energy they need, like benzoates do. And it is used in bakery products as a mold inhibitor.

Toxicity Data With Reference

1.    

orl-rat LD50:3920 mg/kg

    TRENAF    Kenkyu Nenpo-Tokyo-toritsu Eisei Kenkyusho. Annual Report of Tokyo Metropolitan Research Laboratory of Public Health. 27 (1976),159.
2.    

orl-mus LD50:2350 mg/kg

    TRENAF    Kenkyu Nenpo-Tokyo-toritsu Eisei Kenkyusho. Annual Report of Tokyo Metropolitan Research Laboratory of Public Health. 27 (1976),159.

 Calcium propionate (CAS NO.4075-81-4) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. You can see actual entry in RTECS for complete information.

Safety Profile

Risk Statements: 36/37/38
 R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25 
S24/25:Avoid contact with skin and eyes.

Specification

 Calcium propionate , its cas register number is 4075-81-4. It also can be called Calcium dipropionate ; Bioban-C ; and Propanoic acid, calcium salt . It is listed as E number 282 in the Codex Alimentarius as a food additive. It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately.  Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately.
In addition, Calcium propionate (CAS NO.4075-81-4) could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.