Conjugate addition of vinylic organocuprates generated via transmetalation of phenylseleno-substituted vinylzirconates: Functionalization at the 4-position of enones

DOI: 10.1002/hc.20720

Source and publish data:

Heteroatom Chemistry p. 545 - 552 (2011)

Update date:2022-08-03

Topics:

Authors:

Segi, Masahito

Suzuki, Masahiro

Shintaku, Kazuki

Maeda, Hajime

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hc.20720

Hydrozirconation of propargylic selenides (1) or 4-phenylseleno-1-butyne (2) with Cp₂ZrHCl, followed by in situ transmetalation to cuprate (Me₂Cu(CN)Li₂) and addition of enones, led to the formation of 1,4-adducts in good

Full text of DOI:10.1002/hc.20720

Products guided by the article

Product name:3-(1-hydroxyprop-2-enyl)cyclohexanone

Cas No:1334109-12-4

R&D Labs maybe for 1334109-12-4

Shanghai Hanhong Scientific Co.,Ltd.

website:http://www.chemvia.com

Contact:+86-21-64541543,54280654,13918533501

Address:Jiachuan Road 245
Shanghai Science Peptide Biological Technology Co.,ltd

website:http://www.scipeptide.com

Contact:+86-21-51099675

Address:No.8 Changyang Rd
Greenutra Resource Inc

website:http://www.greenutra.cn

Contact:0086-411-39553357

Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China

Relevant to this article

Tertiary phosphine oxides in reaction with benzaldehyde

Doi:10.1023/A:1026340532022
(2003)
A new method for the catalytic aldol reaction to ketones

Doi:10.1021/ja034993n
(2003)
Doi:10.1039/CT9120100735
(1912)
Chiral sulfoxide-olefin ligands: Completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions

Doi:10.1002/anie.201102586
(2011)
ADDITION OF THIOLS AND THIOACIDS TO ETHYL-α-CYANOACRYLATE

Doi:10.1007/BF01184534
(1990)
Degenerate Transesterification of 3,5-Dimethylphenolate/3,5-Dimethylphenyl Esters in Weakly Polar, Aprotic Solvents. Reactions of Aggregates and Complex-Induced Proximity Effects

Doi:10.1021/ja00009a034
(1991)

Article Doi