Alkylation of carbonyl compounds with dialkylzirconocene complexes promoted by potassium t-butoxide

DOI: 10.1016/S0040-4039(00)79419-6

Source and publish data:

Tetrahedron Letters p. 5893 - 5894 (1991)

Update date:2022-08-05

Topics:

Authors:

Larson Larson

Baker Baker

Towne Towne

Straus Straus

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Article abstract of DOI:10.1016/S0040-4039(00)79419-6

Potassium t-butoxide promotes alkylation of non-enolizable ketones and aldehydes by zirconocene dialkyls. The reaction proceeds with loss of cyclopentadienide ion from the metal center.

Full text of DOI:10.1016/S0040-4039(00)79419-6

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