Alkylation of carbonyl compounds with dialkylzirconocene complexes promoted by potassium t-butoxide

DOI: 10.1016/S0040-4039(00)79419-6

Source and publish data:

Tetrahedron Letters p. 5893 - 5894 (1991)

Update date:2022-08-05

Topics:

Authors:

Larson Larson

Baker Baker

Towne Towne

Straus Straus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79419-6

Potassium t-butoxide promotes alkylation of non-enolizable ketones and aldehydes by zirconocene dialkyls. The reaction proceeds with loss of cyclopentadienide ion from the metal center.

Full text of DOI:10.1016/S0040-4039(00)79419-6

Products guided by the article

Product name:2-(cyclopenta-2,4-dien-1-ylidenemethyl)furan

Cas No:13347-56-3

R&D Labs maybe for 13347-56-3

Hebei Fulong Import & Export Co., Ltd.

Contact:86-311-87795661

Address:15A19 Zhongyuan Building,368 Youyi North Street,Shijiazhuang 050070,China
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Shanghai doly chemical Co.,Ltd

Contact:+86-21-34716221

Address:No.328,WuHe Roard,MinHang,ShangHai China
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.

Relevant to this article

Syntheses of Azulene Analogues of Triphenylmethyl Cation: Extremely Stable Hydrocarbon Carbocations and the First Example of a One-Ring Flip as the Threshold Rotation Mechanism for Molecular Propellers

Doi:10.1246/bcsj.68.1409
(1995)
Generation and Trapping of Cyclopropenes from 2-Alkoxy-1,1-dichlorocyclopropanes

Doi:10.1002/hlca.19910740108
(1991)
A facile synthesis of benzo[b]thiophene derivatives

Doi:10.1002/jhet.5570280130
(1991)
FORMATION OF CARBOXAMIDES WITH N,N,N',N'-TETRAMETHYL (SUCCINIMIDO) URONIUM TETRAFLUOROBORATE IN AQUEOUS / ORGANIC SOLVENT SYSTEMS

Doi:10.1016/S0040-4039(00)92032-X
(1991)
Development of a formal catalytic asymmetric [4 + 2] addition of ethyl-2,3-butadienoate with acyclic enones

Doi:10.1021/ol202301f
(2011)
Recognition by New Symmetrically Substituted Chiral Diphenyl- and Di-tert-butylpyridino-18-crown-6 and Asymmetrically Substituted Chiral Dimethylpyridino-18-crown-6 Ligands of the Enantiomers of Various Organic Ammonium Perchlorates

Doi:10.1021/jo00010a028
(1991)

Article Doi